how to dispose of zinc sulfate solution

Use water spray to keep fire-exposed containers cool. Zinc Sulfatereacts violently with PHOSPHORUS and FINELY DIVIDED ALUMINUM or MAGNESIUM. Zinc Sulfate is not compatible with STRONG BASES (such as SODIUM HYDROXIDE and POTASSIUM HYDROXIDE). Nickel and perchlorates are toxic to environment, Not required; can be dumped in trash or taken to waste disposal centers, Yes (if pure); No (if it contains cobalt), Toxic to the environment if it contains cobalt, Generates carbon oxides, nitrogen fumes; May corrode metal container, if done in one, May cause uncontrolled algae growth in water bodies, Decomposes when burned; May explode if heated at high temperatures, Safe, good fertilizer; May cause uncontrolled algae growth in water bodies, Water, iron(III) oxide, manganese dioxide, Decomposes when heated to high temperatures, releasing water vapor, Yes, though not recommended in large quantities, Irritant and corrosive to large organisms, kills small organisms, Not required; should be taken to disposal facilities, Not useful; Turns into oxides of lower states at high temperatures, Not required; and oxidizing mixture may be used to oxidize it completely if desired, Decomposes above 250 C to release carbon dioxide, water vapors and soot, There is little data available for its environmental effects, doesn't appear to be toxic, Lethal to small animals and toxic to larger ones in small amounts; Not suspected to be bioaccumulative, Uncomposted wood is harmful for environment, especially sawdust, Melts at 70 C and gives off harmful cadmium fumes at high temperatures, While bismuth and tin don't present great hazard to environment, lead and cadmium do, Oxidation with Fenton's reagent; Incineration, best with an afterburner, Burns in air, to release combustion gasses, soot and VOCs, Toxic to wildlife and hazardous to water bodies, Cannot be digested by most lifeforms, otherwise little to no toxicity to most organisms; It is however known to be fatal to dogs and some birds, Recycling; Traces of zamak waste can be dissolved with nitric acid, followed by neutralization of leftover acid, recovering copper and zinc via electrowinning, Not useful; melts above 380 C and may fume, Low quality zamak may contain lead or cadmium which are harmful to the environment, Unless contaminated with hazardous compounds, it poses little danger to environment, Breaks down to zinc oxide, carbon oxides, water, acetone, acetic anhydride (?) Zinc Sulfate 0 01M (ZN3001-G) DRUG FACTS Active Ingredient Pyrithione Zinc 1% Purpose Anti-Dandruff Uses Helps to Treat Flakes, Itch, Irritation, Oilness Or Dryness It's best however, to avoid dumping large quantities of waste, as the reaction in exothermic and may splash or volatilize some of the waste, so it's best to perform the neutralization in small steps. (USCG, 1999). Hocking, p. 216, http://www.drugfuture.com/chemdata/cuprous-sulfite.html, http://www.inchem.org/documents/sids/sids/115775.pdf, http://pubs.acs.org/doi/abs/10.1021/es7029703?journalCode=esthag, Safe disposal/handling of lead in a domestic setting, http://www.sciencemadness.org/smwiki/index.php?title=Proper_disposal_of_chemicals&oldid=14787, GNU Free Documentation License 1.3 or later, Oxidation with Fenton's reagent; Concentrated solution of sodium hydroxide, Safe detonation in remote area; Strong dilution in organic solvent followed by safe incineration; Hydrolysis with cold sodium hydroxide solution, Toxic to organisms; nitrate source for plants, Oxidation with an oxidizing solution, such as chromic acid, piranha solution, Fenton's reagent, Incineration (no peroxides); Oxidation with Fenton's reagent; Chlorination in water with chlorine or hypochlorous acid; If peroxides are present, addition of excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Incineration produces carbon dioxide and water vapor. The concentration is determined by volumetric titration and refers to 20C. This wiki will NOT take any responsibility (legal or other) for any (failed) attempts at neutralizing hazardous reagents. It is also used as a dietary supplement, and If magnetic, a magnet can be used to scoop all the pieces, Stainless steel alloys contain chromium which will slowly leak in the environment and may increase the level of chromium in the environment; Some SS alloys may have nickel which is harmful to the environment, Safe, biodegradable; Nourishment for almost all organisms, Recycling; Steel waste don't require chemical neutralization as it's mostly iron which has low environmental impact. Web2. The soluble salts of halogen acids and oxoacids (except perchloric and chloric acids) can be safely poured down the drain. Dissolve the barium salt in the minimum volume of water. Water soluble. Zinc Sulfate -> 10-20% While properly neutralized reagents may be poured down the drain, dumping very large amounts of said reagents is frowned upon. All are noncombustible. Safe, biodegradable; Occurs naturally in various plants, like eucalyptus, peppermint, etc. Eliminate all ignition sources. Breaks down rapidly in the environment due to air and microorganisms, yielding sulfides and sulfates. Many of these compounds catalyze organic reactions. Generally, the soil option is safer, because there is no plumbing you should worry about, but some chemicals shouldn't be released into the soil, either. However, this merely is a method to prevent the heavy metals from being released in the environment and is not a permanent way of disposal. WebCarcinogenicity: Zinc - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. SECTION 11 : Toxicological information Acute Toxicity: Oral: 7779-88-6 LD50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: No additional information. Most chemicals used by the amateur chemist come from every day use and do not require special treatment before being discarded in the usual way. Incineration is attractive as it's a good method of getting rid of wastes, but unless you're using an incinerator, some material will not be destroyed and instead it will be scattered in air. at high temperatures, Unless contaminated, good source of zinc for plants, though a bit too acidic; may lower soil pH, Breaks down to zinc oxide and carbon oxide at high temperatures, Unless contaminated, good source of zinc for plants, though a bit too alkaline, Gives off hydrochloric acid fumes if moist, Chlorides are dangerous for chloride-sensitive plants in large quantities, Sodium, potassium or ammonium carbonate/bicarbonate to precipitate zinc carbonate which is inert; recovery of alkali nitrates, dilution of zinc carbonate and poured down the drain, Decomposes to zinc oxide, releasing nitrogen dioxide and oxigen, May pose a threat to aquatic life in large quantities; may cause unwanted algal bloom; source of zinc and nitrogen to plants, Not required; Weak acids can be used to dissolve zinc oxide stains to soluble zinc compounds, Turns the oxide yellow at high temperatures; process is reversible, May pose a threat to aquatic life in large quantities, Precipitation with a soluble hydroxide; Reduction of perchlorate to chloride, Gives off chlorine oxide fumes, leaving behind zinc oxide slag; may decompose violently if organic contaminant present, Source of zinc and phosphorus for wildlife, Not always required; Zinc metal can be recovered through electrowinning and the diluted sulfuric acid neutralized with a base, Unless contaminated, is a good source of zinc for plants, Dissolving it in water, followed by precipitation of zirconium dioxide by adding an alkali, Potentially harmful; Nitrates may serve as nourishment for plants; Zirconium displays moderate toxicity, Decomposes releasing HCl and water vapors. Heavy metals, such as mercury, can often be neutralized with a mixture of zinc and sulfur powders, which yields mercury sulfide aka cinnabar. Inhalation of dust causes irritation of nose and throat. WebWastes with limited sink/sewer disposal. However, chromic acid will (violently) oxidize alcohols to their respective aldehydes or ketones, which cannot be oxidized further by the acid alone, which limits it's use in neutralizing many compounds. Neutralization with any acid, carbon dioxide; recycling; Not useful; highly corrosive when hot to glass, most common metals, Dangerous to wildlife in short term (highly corrosive); Caesium ions have similar toxicity to those of sodium and potassium, Not required; Can be dumped almost anywhere, Sublimes; Oxidation Generates carbon oxides, water vapors, soot, Toxic to small animals, addictive to large organisms; biodegradable; occurs naturally, Decomposes to calcium carbonate and acetone at high temperature, which burns in an oxygen-rich atmosphere, Not useful; breaks down into calcium carbonate and carbon dioxide as the solution is heated, Lots of water in an open space; low chain alcohols, Dangerous to wildlife in short term (reacts with water); may also release phosphine gas if carbide sample is impure, Not useful; breaks down into calcium oxide and carbon dioxide at high temperatures, Not useful; May release some HCl fumes if wet, Chloride ions may be harmful to certain plants, Neutralization with a reducing agent, such as ascorbic acid sodium metabisulfite, sulfite, bisulfite at acidic pH, Cr(VI) ions are powerful carcinogens and very toxic to organisms, Not useful; Sublimes at very high temperatures, Slowly hydrolyzes to urea, which is a good plant fertilizer, Will result in calcium carbonate and give off carbon dioxide and water vapors at high temperatures, Neutralization with a concentrated alkali or carbonate solution, alcohols, long chain alcohols are preferred; water vapor can also be used; best performed in an open area, Decomposes to release hydrogen at very high temperatures, Will dehydrate to calcium oxide at high temperatures, Sodium bisulfite, sodium metabisulfite, sodium sulfite, Disproportionates into chlorate and chloride; will release chlorine and chlorine dioxide fumes, Not required; soluble carbonate or sulfate solution can be used if necessary, Good source of nitrogen for plants (fertilizer); May cause algal bloom in water bodies, Plenty of cold water, carbon dioxide, sodium/potassium bicarbonate, Mixing it with a combustible material, like sugar and incineration, Will decompose at high temperatures to release oxygen, Not required; can be poured down the drain or dumped in trash, Will decompose at high temperatures to release various ketones, carbon oxides, water vapors, Large quantities are harmful to water bodies and small animals, Not required; soluble carbonate solution can be used if gypsum is not desired as waste product, Becomes anhydrous at high temperatures (drierite); decomposes to calcium oxide at very high temperatures, Anhydrous or hemihydrate form may burn grass on contact, Not required at low concentrations; high concentrations may require an oxidizer, like bleach, Generates irritant smoke, carbon dioxide, soot and water vapor, Harmful for mammals at high concentrations, otherwise relative safe, biodegradable; Occurs naturally, Not possible (gaseous form), safe to pour (water solution), Incineration, followed by scrubbing of sulfur dioxide (optional), Burns in presence of oxygen, releasing carbon dioxide and sulfur dioxide, Oxidation with ozone; adsorbtion on activated charcoal; absorbtion in a solution of cuprous chloride in hydrochloric acid or cuprous chloride in ammonia, Not useful; burns in the presence of oxygen and hydrogen, Sodium hydroxide excess; oxidation with Fenton's reagent, Results in phosgene in the presence of air, Extremely toxic to wildlife, sinks at the bottom of water bodies, Toxic to aquatic life in large quantities, Burns in air; decomposes to release carbon oxides, water vapors, Yes, but avoid water bodies; bury it in ground instead, Safe, biodegradable; avoid dumping large amounts, as it poses choking hazard to most animals, Unnecessary, simply dump in trash; recycle, Unless it adsorbed dangerous volatile compounds or heavy metals, it can be used as a fertilizer, Oxidation with hydrogen peroxide to sulfate, followed by precipitation or reduction of copper ions to metal or hydroxide/oxide, Gives off water vapors when heated and sulfur oxides at very high temperatures, Little is known about its environmental effect; it is used as a fungicide and molluscicide, Reducing with sodium sulfite, metabisulfite, bisulfite, Breaks down to perchloric acid and chlorine oxides, Strong oxidizing, toxic and corrosive to all wildlife and everything organic, Reduction with metabisulfite, sulfite or bisulfite, Neutralization with excess sodium hydroxide to sodium glycolate products, Decomposes high temperatures, releasing toxic fumes, Toxic and corrosive to most wildlife, used as herbicide, Neutralization with a cooled solution of sodium or potassium hydroxide, Evaporates and burns at high temperatures, releasing extremely toxic and lachrymator fumes, Reduction with a reducing agent, such as ascorbic acid, metabisulfite, sulfur dioxide, Gives off hydrogen chloride gases and leaves gold powder behind, Dangerous to wildlife; Best to try to recycle it, Neutralization with Fenton's reagent; biodegradation with the bacterium Rhodococcus phenolicus, Gives off hydrogen chloride fumes during burning/pyrolysis, as well as various POCs and soot, Toxic to wildlife; chlorobenzene can persist in soil for several months, in air for about 3.5 days, and in water for less than one day, Reducing with alkali hydroxide or magnesium, followed by incineration, Gives off hydrogen chloride fumes during burning/pyrolysis, Boils to form vapor, should not be attempted indoors, May cause ozone depletion, dangerous to aquatic life, Release outside in atmosphere; Photolysis; Destruction with aqueous sodium hydroxide, oxidation with, May cause ozone depletion, dangerous to land and aquatic life, Reduction to platinum metal, followed by recovery of the precious metal, Breaks down to platinum(II) chloride, then platinum metal, Decomposes to perchloric acid, hydrogen chloride, chlorine dioxide, oxygen, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid, Precipitation with a base; can be dumped in the trash, taken to a waste disposal facility or recycled, Melts and decomposes at high temperatures, At temperatures ~1000 C it will become inert against the action of most reagents, Low reactivity, low danger for environment, Precipitation with a soluble hydroxide, followed by calcination to chromium(III) oxide, Due to its instability, it poses low danger to environment, Dissolving it in water and reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid at acidic pH, A supersaturated solution of a reducing agent, such as sodium sulfite, metabisulfite or thiosulfate at acidic pH, Not useful, boils off and fumes in contact with air moisture, Corrosive and deadly to all wildlife; Lowers soil pH; Corrosive to rocks, soil; Carcinogenic, Any base, carbonate, bicarbonate, alkaline-earth oxide, In wet environment it acts as fungi growth environment, Dumped in trash, incineration, taken to waste disposal centers, Gives off carbon dioxide and water vapors, leaving ash behind, May give off hydrogen chloride fumes in the presence of water, Toxic to wildlife; classified as "Substance of very high concern" in the EU, Any soluble hydroxide, carbonate; Taken to disposal centers, Gives off sulfur oxides fumes and sulfuric acid vapors, leaving behind cobalt oxide residue, Cobalt is necessary for vitamin B12 production, Not always required; can be dumped in trash, Recover copper via reduction; Discard in trash, Decomposes to copper oxide and releases various gasses, High levels of copper are dangerous to wildlife, Reduction with a iron or zinc to metallic copper, Gives off HCl fumes and leaves behind CuO slag, May hydrolyze in the presence of water and air to give off hydrogen chloride fumes, Oxidizes to copper(II) chloride in the presence of air, which is toxic and corrosive in water, Dissolving it in an acid, followed by reduction to metallic copper, Reduction with iron or zinc to metallic copper, which is recycled, Gives off carbon oxides, water, acetic acid and acetone vapors, Unknown effects in the environment; presence of copper ions however is generally considered harmful, Pyrolysis, incineration, oxidation with Fenton's reagent, Gives off carbon oxides and water vapors, as well as soot and VOCs, Not required; can be neutralized with an acid and reduced to metallic copper, Will give off carbon dioxide fumes and leave CuO residues, Copper ions are considered harmful to the environment, Precipitate as carbonate or reduce to copper metal using aluminium, iron or zinc, Loses water and hydrogen chloride, turns brown, Yes, but far from any agricultural plants, Copper ions are considered harmful to most wildlife, Any alkali or ammonium hydroxide, carbonate, Gives off nitrogen oxide and nitric acid fumes, leaving copper oxides/hydroxides slag, Copper ions may be harmful to wildlife; the nitrate group is a nitrogen source for plants, May decompose to copper oxide and phosphorus oxides at high temperatures, or elemental phosphorus in the presence of a reducing agent, Due to low solubility, it has lower toxicity than other copper compounds, Reduction with aluminium, iron or zinc to metallic copper, Loses water when heated, releases sulfur trioxide at high temperatures, leaving behind CuO, Releases carbon oxides and water vapors, as well as soot, Incineration outside; oxidation with an oxidizing solution, Flammable, burns in the presence of oxygen to release carbon dioxide and nitrogen gas, Not required; Any base, carbonate, bicarbonate, alkaline-earth oxide can be used if desired, Oxidation with Fenton's reagent or piranha solution, Considered to be harmful, but little is known about its toxicity, Dilution with a flammable solvent and incineration; oxidation with Fenton's reagent, Flammable, burns in the presence of oxygen to release carbon oxides, water vapors, soot and VOCs, Dilution with a flammable solvent and incineration, Low toxicity to organisms, but may be harmful to wildlife, Ignites at high temperatures and generates carbon oxides, water vapors, carbon monoxide, soot, VOCs, Incineration; Oxidation with Fenton's reagent, Ignites in air, gives off carbon dioxide and water vapors, soot, Dissolved in acid, followed by recovery of copper and zinc, Decomposes to release carbon oxides, water vapors, Toxic to small animals, otherwise relative safe, Burned outside or in an incinerator; hydrolysis in water, Careful dissolving in cold water/crushed ice, followed by neutralization with base; Reduction with metabisulfite, sulfite or bisulfite, Neutralization and dehalogenation with excess sodium hydroxide; Reduction with metallic powders to acetic acid, Destruction with aqueous sodium hydroxide, iron can also be used; Oxidation with, Boils to form vapor; pyrolysis at high temperatures yielding chlorine, hydrochloric acid and carbon monoxide, Extremely flammable, burns to release carbon dioxide, nitrogen gas and lots of heat, Yields carbon oxides, water vapor at high temperatures, Toxic to organisms, dangerous to aquatic and soil life, Incineration (no peroxides); Adding excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Extremely flammable, burns to release carbon dioxide and water vapors, Neutralization with base, bacterial degradation, decarboxylation, taken to waste disposal centers, Decomposes, releases combustion gasses, HF, methylene fluoride, Displays moderate toxicity to most organisms, Incineration (no peroxides); Acid-catalyzed hydrolysis with sulfuric acid; If peroxides are present, addition of excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Incineration; can be released in open air, Addition in large amounts of water or crushed ice, followed by addition of aq. NaOH, Decomposes to release nitrogen/chlorine oxides and oxygen, Aqueous base; percarbonates can also be used to remove nitric oxide; multiple washings may be required, Decomposes, giving off nitrogen oxide and chlorine/HCl fumes, Highly corrosive and toxic to all organisms and materials, Careful addition to crushed ice, followed by neutralization with a diluted base, Deadly and extremely corrosive to all organisms, Diluted and hydrolyzed; Careful and controlled pyrolysis, Any base, hydroxide, carbonate, bicarbonate; percarbonates can also be used, Decomposes, giving off nitrogen oxide fumes, Corrosive to organisms and rocks; salts somewhat toxic to animals, Gentle reduction with various reducing agents, Breaks down to nitrogen and oxygen at high temperatures, Low toxicity to wildlife, may induce light narcotic effects and laughing sensation in some organisms, Mixed with a more flammable solvent, followed by incineration, Safe, occurs naturally in citrus fruit peels, Pyrolysis; diluted and poured down the drain, Decomposes on heating to release carbon oxides and various organic compounds, May pose a threat to wildlife in large amounts, Reduced with hydrogen or another reducing agent, Neutralization with any oxide, hydroxide, carbonate, followed by pyrolysis, Releases carbon oxides and water vapor at high temperature, Toxic to wildlife; Small amounts occur in some plants, Disolving it in large amounts of water, followed by neutralization with any oxide, hydroxide, carbonate, Toxic and corrosive to wildlife and environment, Any compound easily oxidizable that does not ignite, such as carbon monoxide, activated charcoal, Accelerates the decomposition of ozone, but not enough, Dangerous to wildlife, may oxidize various gaseous compounds, contributing to the acid rain; In the upper atmosphere it acts as UV shield, Will burn if ignited, releasing carbon oxides, water vapors and soot, Excess paper is harmful for environment, unless composted first, Wax, both solid and molten, floats on water bodies and may inhibit the cellular breathing of many organisms, Mixed with a flammable solvent and incinerated, Gives off carbon oxides, water vapors, aldehydes, Low toxicity to aquatic life; Classified as biodegradable, Oxidation with Fenton's reagent; Mixed with a flammable solvent and incinerated; Reduction with powdered iron, Gives off carbon oxides, water vapors, soot, Displays relative low toxicity to aquatic life; PETN undergoes safe biodegradation, Flammable, releases carbon oxides, water vapor when burned in air, Bicarbonates, carbonates, bases, oxides; neutralized solution can be safely poured down the drain; valeric salts can also be pyrolyzed in a kiln, Flammable (high concentrations, >86 C), no dangerous combustion products, though the smoke will have a rancid smell, Dangerous for wildlife and aquatic life in large concentrations, Dilution in water, followed by neutralization with a base; iron oxide can be added to decompose hydrogen peroxide; can be poured down the drain afterwards, May explode at high temperatures, at high concentrations, Toxic and corrosive to wildlife, both animals and plants, Neutralization with potassium, calcium bases, followed by reduction with metallic iron under UV light in the absence of air, Leads to decomposition, resulting in manganese dioxide slag, The resulting manganese dioxide from the decomposition can be toxic if ingested by animals, Strong oxidizer, it is dangerous and toxic to small organisms, Oxidation with Fenton's reagent or piranha solution, followed by neutralization and poured down the drain, Gives off carbon oxides, water vapors, soot, VOCs, PAHs, nitrogen, Dangerous to environment, very toxic to aquatic life, Flammable if preheated, gives off carbon dioxide, soot and water vapors, Gives off carbon oxides, water vapors, soot and VOCs, Dilute it with plenty of water before release, Dangerous to environment in large amounts, Not always required, may be strongly diluted and poured down the drain, Breaks down to carbon oxides, water vapors, soot; may give off aromatic vapors, Low toxicity, may occur naturally in small amounts, Oxidation with Fenton's reagent; Incineration, best done with an afterburner, Flammable, burns in air to release carbon oxides, water vapors, soot, VOCs, Toxic to wildlife and very dangerous to aquatic life, as well as soil. 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Inhalation of dust causes irritation of nose and throat at neutralizing hazardous reagents naturally in various plants like. And refers to 20C: Oral: 7779-88-6 LD50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: Oral 7779-88-6... Iarc, NTP, or CA Prop 65 be safely poured down the drain failed... Sulfides and sulfates zinc Sulfatereacts violently with PHOSPHORUS and FINELY DIVIDED ALUMINUM MAGNESIUM!

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